Research progress on detection methods of trace unsymmetrical dimethylhydrazine
DOI: 10.23977/erej.2022.060306 | Downloads: 14 | Views: 519
Wei Lao 1, Hu Cui 1, Xuanjun Wang 1
1 Rocket Engineering University, 710025, Xi'an, Shaanxi, China
Corresponding AuthorWei Lao
Unsymmetrical dimethylhydrazine (UDMH) is an excellent liquid rocket propellant, but its toxicity is strong, which is harmful to human health and seriously pollutes the environment. However, the spectrophotometric method for detecting UDMH in the current Chinese national standards can’t meet the detection requirements under high safety standards. This article not only reviews the research methods at home and abroad, but also discusses the advantages and disadvantages of these methods.
KEYWORDSUnsymmetrical dimethylhydrazine, Chromatography, Spectrum method, Electrochemical method, Analysis and detection
CITE THIS PAPER
Wei Lao, Hu Cui, Xuanjun Wang, Research progress on detection methods of trace unsymmetrical dimethylhydrazine. Environment, Resource and Ecology Journal (2022) Vol. 6: 46-53. DOI: http://dx.doi.org/10.23977/erej.2022.060306.
 Chen Tong, Geng Kui, Gao Ying, et al. Emergency rescue and disposal technology for liquid propellant accident, A. Chinese Institute of Command and Control. 2013 First China Command and Control Conference Proceedings, C. Chinese Institute of Command and Control, 2013: 4.
 GB 18059-2000, Hygienic Standard for unsymmetric dimethylhydrazine in air of residential area, S. Beijing: China Standard Press, 2000.
 Mildred K. P, Jay M. L, Philip D, et al. A Colorimetric Determination for 1,1-Dimethylhydrazine (UDMH) in Air, Blood and Water, J. American Industrial Hygiene Association Journal, 1963, 24 (3): 239-244.
 Brenner K. P, Rose-Pehrsson S. L. Development of a Dosimeter System for Unsymmetrical Dimethylhydrazine, Monomethylhydrazine and Hydrazine, AD-A281249 R. Washington, D. C: Naval Research Lab, 1994.
 Li Baoting, Cao Ye, Peng Qingtao. Manufacturing and testing of liquid propellant gas detection tube, C// Proceedings of the 8th National Conference on Chemical Propellants of the Chinese Chemical Society. 2017.
 Yao X, Zhang G, Liu B, et al. Direct detection of 1,1-dimethylhydrazine in water samples based on formation of gold nanoparticles, J. Materials Research Express, 2019.
 Zhang Youzhi, Li Zhengli, Wang Xuanjun, et al. Research Progress in Detection Technology of Trace Unsymmetrical Dimethyl Hydrazine, J. Chemical Propellants & Polymeric Materials, 2008 (03): 20-23.
 Mazur J. F, Podolak G. E, Heitke B. T. Use of a GC concentrator to improve analysis of low levels of airborne hydrazine and unsymmetrical dimethylhydrazine, J. Aihaj, 1980, 41 (1): 66-69.
 Sotnikov E. E, Moskovkin A. S. Gas-chromatographic determination of 1,1-dimethylhydrazine in water, J. Journal of Analytical Chemistry, 2006, 61 (2): 129-132.
 Bakaikina N. V, Kenessov B, NV Ul’Yanovskii, et al. Quantification of Transformation Products of Unsymmetrical Dimethylhydrazine in Water Using SPME and GC-MS, J. Chromatographia, 2017, 80 (6): 931-940.
 Polunin K. E, Ul’yanov A. V, Polunina I. A, et al. Detection and Neutralization of Unsymmetrical Dimethylhydrazine on the Surface of Construction Materials, J. Russian Journal of Physical Chemistry A, 2021, 95 (3):
 Ul'yanovskii N. V, Kosyakov D. S, Popov M. S, et al. Rapid quantification and screening of nitrogen-containing rocket fuel transformation products by vortex assisted liquid-liquid microextraction and gas chromatography-high-resolution Orbitrap mass spectrometry, J. Microchemical Journal, 2021, 171:
 Cao Ye, Wang Li, Han Zhuozhen, et al. GC-MS Determination of Unsymmetrical Dimethylhydrazine in Air, J. Physical Testing and Chemical Analysis (Part B: Chemical Analysis), 2010, 46 (10): 1184-1186.
 Zhang Wei, Wu Wan’e, Jia Ying, et al. Study on the Influence of Headspace Conditions on the Determination of Unsymmetrical Dimethyl Hydrazine in Water, J. Chemical Propellants & Polymeric Materials, 2011, 9 (03): 93-95.
 Zhang Yu, Cheng Xiaoyan, Yang Ping, et al. Determination of Hydrazine and Unsymmetrical Dimethyl Hydrazine in Surface water by Furfural Derivation and Gas Chromatography/Mass Spectrometry (GC/MS), J. Sichuan Environment, 2011, 30 (1): 5.
 Zhang Guangyou, Peng Qingtao, Cao Ye. Determination of Unsymmetrical Dimethylhydrazine in Ambient Air by Solid Adsorption-Capillary Gas Chromatography, J. Chemical Analysis and Meterage, 2012, 21 (2): 69-71.
 A. A. Denisov, A. D. Smolenkov, O. A. Shpigun. Determination of 1,1-Dimethylhydrazine by Reversed-Phase High-Performance Liquid Chromatography with Spectrophotometric Detection as a Derivative with 4-Nitrobenzaldehyde, J. Journal of Analytical Chemistry, 2004, 59 (5): 452-456.
 Smirnov R. S, Smolenkov A. D, Bolotnik T. A, et al. Precolumn derivatization with glyoxal as a new approach to the highly sensitive HPLC-UV determination of unsymmetrical dimethylhydrazine, J. Journal of Analytical Chemistry, 2013, 68 (9): 837-844.
 Osipenko S. V, Smirnov R. S, Smolenkov A. D, et al. Highly sensitive determination of 1,1-dimethylhydrazine by high-performance liquid chromatography-tandem mass spectrometry with precolumn derivatization by phenylglyoxal, J. Journal of Analytical Chemistry, 2016, 71 (13): 1228-1232.
 Amosov A. S, Ul’yanovskii N. V, Kosyakov D S, et al. Simultaneous Determination of Hydrazine, Methylhydrazine, and 1,1-Dimethylhydrazine by High-Performance Liquid Chromatography with Pre- and Post-Column Derivatization by 5-Nitro-2-Furaldehyde, J. Journal of Analytical Chemistry, 2018, 73 (5): 497-503.
 Han Yingchen, Zhong Lin, Shen Jimin, et al. Determination of trace unsymmetrical dimethylhydrazine in water by high performance liquid chromatography, J. Journal of Harbin Institute of Technology, 2013, 45 (8): 34-38.
 Subramanian S, Narayanasastri S, Reddy A. Single step derivatization with CF3 enone of thiophene at ambient temperature to determine propellant grade hydrazines: a study by GC and GC-MS, J. Analyst, 2014, 140 (1): 330-339.
 Cao Ye, Zhang Guangyou, Wang Li, et, al. Determination of Trace Unsymmetrical Dimethyl Hydrazine in Air by Gas Chromatography/Mass Spectrometry, J. Analytical Chemistry, 2010 (12): 140-143.
 Min L, Ostovic J, Chen E. X, et al. Hydrophilic interaction liquid chromatography with alcohol as a weak eluent, J. Journal of Chromatography A, 2009, 1216 (12): 2362-2370.
 Wei Guihuan, Long Qingyun, Yang Pin, et al. Determination of Unsymmetrical Dimethylhydrazine in Air of Closed Environment with Gas Chromatography after Derivation, J. Ship defense, 2015 (1): 5.
 Feng Changgen, Liao Qili, Wang Li. Determination of Unsymmetrical Dimethyl Hydrazine in Soil by Alkaline Distillation/Ultrasonic Derivatization-Gas Chromatography-Mass Spectrometry, J. Chinese Journal of Analytical Chemistry, 2016 (9): 1425-1431.
 Kosyakov D. S, Ul'Yanovskii N. V, Bogolitsyn K. G, et al. Simultaneous determination of 1,1-dimethylhydrazine and products of its oxidative transformations by liquid chromatography-tandem mass spectrometry, J. International Journal of Environmental Analytical Chemistry, 2014, 94 (11-15): 1254-1263.
 NV Ul’Yanovskii, Kosyakov D S, Pikovskoi I I, et al. Determination of 1,1-Dimethylhydrazine and its Transformation Products in Soil by Zwitterionic Hydrophilic Interaction Liquid Chromatography/Tandem Mass Spectrometry, J. Chromatographia, 2018.
 Timchenko Y. V, Stavrianidi A. N, Smolenkov A. D, et al. A novel simple and sensitive approach for determination of 1,1-dimethylhydrazine in aqueous samples by high performance liquid chromatography with ultraviolet and tandem mass spectrometric detection after derivatization with unsubstituted aromatic aldehydes, J. Chemosphere, 2021, 280:
 Sun Suli, Chen Yuan, Zhao Wenying, et al. Determination of Unsymmetrical Dimethylhydrazine by Ion Chromatography, J. Journal of Qingdao University of Science and Technology (Natural Science Edition), 2016, 37 (001): 23-25.
 Smolenkov A. D, Rodin I. A, RS Smirnov. Use of ion and ion-pair chromatography with mass spectrometric detection to determine unsymmetrical dimethylhydrazine and its transformation products, J. Moscow University Chemistry Bulletin, 2012, 67 (5): 229-235.
 Kosyakov D. S, Khviyuzov S. S, NV Ul’Yanovskii, et al. Supercritical Fluid Extraction of 1,1-Dimethylhydrazine from Peaty Soils, J. Russian Journal of Physical Chemistry B, 2013, 7 (7): 880-884.
 Ashwini, Kumar, Jacob, et al. Determination of hydrazines by chip electrophoresis with contactless conductivity detection, J. Electrophoresis, 2011, 32 (8): 920-925.
 Kosyakov D. S, Pikovskoi I. I, Ul'Yanovskii N. V, et al. Direct determination of hydrazine, methylhydrazine, and 1,1-dimethylhydrazine by zwitterionic hydrophilic interaction liquid chromatography with amperometric detection, J. International Journal of Environmental Analytical Chemistry, 2017, 97 (1-5): 313-329.
 Zhang Youzhi, Wang Xuanjun, Liu Xiangxuan, et al. The Establishment of the Automatic Potentiometry for Unsymmetrical Dimethylhydrazine Analysis, J. Journal of Instrumental Analysis, 2006, 25 (004): 111-114.
 Dong Chao, Ren Xianghong, Hu Lijun. Study on Detection of Unsymmetrical Dimethyl Hydrazine by Electrochemical Sensor Based on Prussian Blue Modified Carbon Paste Electrode, J. Science Technology and Engineering, 2016, 16 (036): 99-104.
 Ren Xianghong, Dong Chao, Hu Lijun, et al. Research on Detection of Unsymmetrical Dimethyl Hydrazine by Current Sensor Based on Prussian Blue/Titanium Dioxide Nanotube Modified Carbon Paste Electrode, J. Journal of Analytical Science, 2017, 04 (v.33): 73-77.
 Hu Liming, Liu Xiangxun, Zhang Langlang, et al. Determination of Trace Unsymmetrical Dimethyl Hydrazine in Water by Differential Pulse Voltammetry with Carbon Nanotube-Nafion Modified Glassy Carbon Electrode, J. Chemical Propellants & Polymeric Materials, 2018.
 Liu Quan, Xu Guogen, Xia Liben, et al. Measurement of Trace UDMH in Water with Flow-injection Chemiluminescent Method, J. Safety and Environmental Engineering, 2009, 16 (05): 73-75.
 Wu wan’e, Meng Xiaohong, Zhang Huitan. Detection of Trace Unsymmetrical Dimethyl Hydrazine in Water by Post Chemiluminescence Method, J. Chinese Journal of Energetic Materials, 2012, 20 (006): 789-793.
 Zhang Huitan, Wu wan’e, Zhang Wei. Potassium Bromate-Luminol Post Chemiluminescence Method for Determination of Trace Unsymmetrical Dimethyl Hydrazine in Water, J. Journal of Analytical Science, 2011 (03): 112-115.
 Kosyakov D. S, Amosov A. S, NV Ul’Yanovskii, et al. Spectrophotometric determination of hydrazine, methylhydrazine, and 1,1-dimethylhydrazine with preliminary derivatization by 5-nitro-2-furaldehyde J. Journal of Analytical Chemistry, 2017, 72 (2): 171-177.
 Taheri E, Bahrami A, Shahna F. G, et al. Evaluation of a novel hollow fiber membrane technique for collection of 1,1-dimethylhydrazine in air, J. Environmental Monitoring and Assessment, 2018.
 Han Zhuozhen, Cao Ye, Wang Li, et al. Solution Absorption/Spectrophotometry Method for Monitoring Analysis of UDMH in Air, J. Environmental Science & Technology, 2010 (11): 4.
 Liu Weiguo, Li Baoting, Cong Rimei. Promote online detection of unsymmetrical dimethyl hydrazine content in wastewater, C// The 5th National Conference on Chemical Propellant. 2011.
 Yao X, Zhang G, Liu B, et al. Key Factors for Rapid Detecting 1,1-dimethylhydrazine in Air by Solution Absorption/Spectrophotometry Method, J. IOP Conference Series Earth and Environmental Science, 2019, 237 (2): 022046.
 Collins G. E, Rosepehrsson S. L. Fluorescent detection of hydrazine, monomethylhydrazine, and 1,1-dimethylhydrazine by derivatization with aromatic dicarbaldehydes, J. Analyst, 1994, 119 (8): 1907-1913.
 Zhang Jingqi, Zhang Shujuan, Wang Gang, et al. Preparation of A Fluorescent Sensing Film on Hydrazine Gas Detection, C// The 29th Annual Conference of the Chinese Chemical Society. 2020.
 Valakh V. V, Voropai E. S, Syrykh Y. P. Detection of the vapor of asymmetric dimethyl hydrazine in the atmosphere by the method of spectrophotometry in the near IR range, J. Journal of Applied Spectroscopy, 1999, 66 (6): 923-927.
 Ren Manyan, Zhang Tianshu, Wang Wei, et al. The Method of Monitoring Dimethylhydrazine Basing on Open Path Fourier Transform Infrared Spectrometry Technology, J. Infrared Technology, 2012, 34 (005): 306-309.
 Cao Ye, Zhang Guangyou, Li Zhen. Study of Serial Toxic Monitoring Instruments for Liquid Rocket Propellant, J. Chinese Medical Equipment Journal, 2012, 33 (010): 7-9.
 Turusova E. V, Nasakin O. E. Using of photogenerated iodine for determination of 1,1-dimethylhydrazine in environmental objects, J. Zavodskaya Laboratroiya. Diagnostika Materialov, 2020, 86 (4):2 1-28.