Author(s)

Orodu Victor Enearepuadoh ¹, Dikio Ezekiel Dixon ¹

Affiliation(s)

¹ Chemical Sciences Department, Faculty of Science, Niger Delta University, Wilberforce Island, P.M.B 071, Amassoma, Bayelsa State. Nigeria

Corresponding Author

Orodu Victor Enearepuadoh

ABSTRACT

Metal organic framework (MOFs) of copper was synthesized using benzene 1, 4- dicarboxylic acid as a linker and N, N-dimethylformamide as a solvent. The Synthesis of copper MOFs was carried out using solvothermal method. The synthesized Cu-MOFs was characterized using the Fourier transform infra-red spectroscopy(FTIR), Scanning electron microscopy SEM, and Energy Dispersive X-ray spectroscopy, EDX, was utilized for morphology and elemental analysis respectively. The elemental composition was Cu = 23.6 %, C= 54.1% & O= 22.3 %. Synthesized Cu-MOF was used in crude oil adsorption study by simulation of spillage with 50 mL of distilled water. The result showed that Cu-MOFs is an effective adsorbent for crude oil.

KEYWORDS

Cu-MOF, simulation, Benzene-1, 4-dicarboxylic acid, crude oil

CITE THIS PAPER

Orodu Victor Enearepuadoh and Dikio Ezekiel Dixon. Synthesis, Characterization and Adsorption Study of Metal Organic Framework of Copper (II) benzene-1, 4-dicarboxylate (Cu-MOF) on Crude oil. Progress in Materials Chemistry and Physics (2021) 2: 1-14. DOI: http://dx.doi.org/10.23977/pmcp.2021.020101.

REFERENCES

[1] BenzaouiThouria, AmmarSelatina, DjaafarDjabali, (2017) Adsorption of Copper (II) ion from aqueous solution using bottom ash of expired drugs incineration,Adsorption science andtechnology.36(1-2), 114-129.
[2] Brinda, L, K.S. Rajan and John Boscobalaguru Rayappan, (2015); Synthesis and Characterization of MOF-199: A Potential Sensing Material.Journal of Applied Sciences, 12: 1778-1780. 
[3] Cotton, Albert .F; Geoffrey, Wilkinson, (1972), Advance inorganic Chemistry Text. J. Chem. Educ.44,3,A240
[4] Eram Sharmin and FahminaZatar, (2015) Metal organic frame work(MOFs). Inorganic material research laboratory,http://dx.doi.org/10.5772/64797.
[5] Ezekiel Dixon Dikio and Abdullahi Farah, (2013) Synthesis, characterization and comparative of Copper and Zinc metal organic frameworks., Chemical Science Transaction. 2(4),1386-1394
[6] Keskin and Kiziel(2010): A planar π – conjugated Nephthyridine – based – N Heterocyclic carbine Ligand and its Derived Transition – Metal complexes. Organometallics, 32 (1)209-21.
[7] Lauren Nicole McHugh, Paul Stewarts.S. Wheatley, Leonardo Perez, David B Radford Cordes. (2019); Synthesis and structural characterization of the copper MOF:STAM-NMe2,CrystEngComm. 21(36).
[8] Lee .J .D; (1996); Concise inorganic chemistry . 5th edition ,816-822.
[9] Liu, Xin, "Syntheses,(2015).,Structures and Properties of Metal-Organic Frameworks"  Masters Theses & Specialist Projects. Paper 1499.
https://digitalcommons.wku.edu/theses/1499
[10] Norbert Stock and Shyam Biswas ;(2012): Synthesis of metal organic organic framework; Roles to various MOF topologies, morphologies and composites.Chem. Rev. 112,2,933-969.
[11] Rasha Abulahim, (2016), Metal organic frame work; Exploration and design strategies for MOFs synthesis. ScieTec , 35-41.
[12] Shooto, Ntaote David, Dikio Ezekiel Dixion, Donbebe and Sikhwivhilu,Lucky; (2015) synthesis morphology and lead ion adsorption properties of metal organic framework of copper and cobalt. Chemsci; J6; 113.doi ;10, 4172/2150-3494. 1000113.
[13] Savita.J. Singh, Sandip.R. Kale,Manoj .B. Gawande, A.VelhinhoRadha V. Jayaram;(2014) Synthesis of Copper base metal organic framework for O-acetylation of alcohols.Article in catalysis communication 44: 24-28
[14] Tabinda Satta’s,  MuhammedAthar;(2017) Hydrothermal synthesis and characterization of Copper glycination (BIO-MOF-29) and it’s in-vitrodrugs adsorption studies; Open Journal of Inorganic Chemical.  07 (02);17-27.
[15] Vincent,G.DongWook, Janod .K,Ryan.E, Vintang Liu, Karimadil, young .M, and Mohammed .S. E;(2016) application of metal organic framework .32, 233-242
[16] Wenlong, Xiang. Yuepingzhangi ,Hongfeilin and Chang-Junlis, (2017): Manganese oxide – modified biochars, preparation, characterization and sorption of arsenate and lead. Bioresourtechnol181.13-17.
[17] Wei-Qinxu, shan He, Chun-Cheng Lin, Yan-XuanQiu,Xiao-Jun Liu, Tao Jiang, Wen-Ting Liu, Zhang, Ji-Jun Jiang;(2018): A Copper based metal organic framework: Synthesis modification and VOCs adsorption. Article in Inorganic Chemistry communication; 92, 1-4
[18] Xin Liu, (2015) , Synthesis ,structure and properties of metal organic framework ; Masters  Theses & specialist Project.paper 1499.
[19] Yaghi, O. M., Eubank J.F and Forster, P. (1998). Chem. Soc. Rev., 38, 1213-1214.

Sponsors, Associates, and Links

---

• Forging and Forming
  
  
• Composites and Nano Engineering
  
  
• Journal of Materials, Processing and Design
  
  
• Metallic foams
  
  
• Smart Structures, Materials and Systems
  
  
• Chemistry and Physics of Polymers
  
  
• Analytical Chemistry: A Journal
  
  
• Modern Physical Chemistry Research
  
  
• Inorganic Chemistry: A Journal
  
  
• Organic Chemistry: A Journal
  
  
• Transactions on Industrial Catalysis
  
  
• Fuels and Combustion
  
  
• Casting, Welding and Solidification
  
  
• Journal of Membrane Technology
  
  
• Journal of Heat Treatment and Surface Engineering
  
  
• Trends in Biochemical Engineering
  
  
• Ceramic and Glass Technology
  
  
• Transactions on Metals and Alloys
  
  
• High Performance Structures and Materials
  
  
• Rheology Letters
  
  
• Plasticity Frontiers
  
  
• Corrosion and Wear of Materials
  
  
• Fluids, Heat and Mass Transfer
  
  
• International Journal of Geochemistry
  
  
• Diamond and Carbon Materials
  
  
• Advances in Magnetism and Magnetic Materials
  
  
• Advances in Fuel Cell
  
  
• Journal of Biomaterials and Biomechanics