Research Progress of Metamorphic Treatment of Hypereutectic Aluminum-Silicon Alloys
DOI: 10.23977/jmpd.2025.090112 | Downloads: 15 | Views: 281
Author(s)
Jian Li 1,2, Yongfa Zheng 1,2, Zichen Ming 3, Shaodong Hu 1,2
Affiliation(s)
1 Guangxi Colleges and Universities Key Laboratory of Environmental Friendly Materials and Ecological Restoration, School of Materials and Environment, Guangxi Minzu University, Nanning, Guangxi, China
2 Guangxi Key Laboratory of Advanced Structural Materials and Carbon Neutralization, School of Materials and Environment, Guangxi Minzu University, Nanning, Guangxi, China
3 CNPC Offshore Engineering Company Limited, Tianjin, China
Corresponding Author
Shaodong HuABSTRACT
Hypereutectic aluminum-silicon (Al-Si) alloys are widely employed in high-end engineering applications, such as automotive engine pistons and aerospace structural components, due to their advantageous properties including low thermal expansion coefficient, high specific strength, excellent castability, and superior wear resistance. The mechanical performance of these alloys is critically influenced by the morphological characteristics of silicon phases, particularly the size, distribution, and geometric features of primary silicon crystals and eutectic silicon networks. This review systematically evaluates recent international research advancements in microstructure optimization of hypereutectic Al-Si alloys. It comprehensively discusses various modification strategies, such as non-rare-earth element modification, rare-earth compound modification and composite modification systems combining multiple alloying elements. Additionally, advanced processing techniques are analyzed, including rapid solidification technologies, ultrasonic vibration treatment during solidification, mechanical stirring processes and high-temperature melt treatment. These approaches have demonstrated effectiveness in refining silicon phase morphologies and improving alloy performance. However, significant challenges remain in achieving uniform microstructure refinement for large-scale castings, particularly in maintaining phase stability during industrial production. Future research should prioritize the development of novel modification systems and integrated processing technologies that can simultaneously optimize both primary and eutectic silicon phases.
KEYWORDS
Hypereutectic Aluminum-Silicon Alloys; Silicon Phase; RefinementCITE THIS PAPER
Jian Li, Yongfa Zheng, Zichen Ming, Shaodong Hu, Research Progress of Metamorphic Treatment of Hypereutectic Aluminum-Silicon Alloys. Journal of Materials, Processing and Design (2025) Vol. 9: 113-122. DOI: http://dx.doi.org/10.23977/jmpd.2025.090112.
REFERENCES
[1] Zhang Y Z. Semi-solid Al-25Si billet preparation and its plastic extrusion molding research [D]. Kunming University of Science and Technology. 2023.
[2] Prashanth K G, Scudino S, Chaubey A K, et al. Processing of Al-12Si-TNM composites by selective laser melting and evaluation of compressive and wear properties[J]. Journal of Materials Research, 2016, 31(1): 55-65.
[3] Kang N, Coddet P, Chen C, et al. Microstructure and wear behavior of in-situ hypereutectic Al-high Si alloys produced by selective laser melting[J]. Materials & Design, 2016, 99: 120-126.
[4] Kang H S, Yoon W Y, Kim K H, et al. Microstructure selections in the undercooled hypereutectic Al-Si alloys[J]. Materials Science and Engineering: A, 2005, 404(1-2): 117-123.
[5] Li Q, Li J, Li B, et al. Mechanical properties and microstructural evolution of Yb-modified Al-20% Si alloy[J]. Journal of Materials Engineering and Performance, 2018, 27: 3498-3507.
[6] Shi W X, Du C W, Lv G Z, et al. Modification of hypereutectic Al-20% Si alloy by neodymium[J]. Advanced Materials Research, 2015, 1095: 180-183.
[7] Mao F, Liu S, He Y, et al. Effect of rare earth Dy (dysprosium) on the microstructures and mechanical properties of hypereutectic Al-Si alloy [J]. International Journal of Metalcasting, 2025, 19(2): 1048-1066.
[8] Kaur P, Dwivedi D K, Pathak P M. Effects of electromagnetic stirring and rare earth compounds on the microstructure and mechanical properties of hypereutectic Al-Si alloys[J]. The International Journal of Advanced Manufacturing Technology, 2012, 63: 415-420.
[9] Dang B, Jian Z, Xu J, et al. Effect of phosphorus and heat treatment on microstructure of Al-25% Si alloy[J]. China Foundry, 2017, 14(1): 10-15.
[10] Aiqin W, Zhang L, Jingpei X I E. Effects of cerium and phosphorus on microstructures and properties of hypereutectic Al-21% Si alloy [J]. Journal of Rare Earths, 2013, 31(5): 522-525.
[11] Wu Y, Wang S, Li H, et al. A new technique to modify hypereutectic Al-24% Si alloys by a Si-P master alloy[J]. Journal of Alloys and Compounds, 2009, 477(1-2): 139-144.
[12] Wang J, Yang W, Tu H, et al. Effect of complex modification of Al-5Ti and Al-3P on hypereutectic Al-18Si alloys[J]. Journal of Central South University, 2019, 26(10): 2651-2660.
[13] Yan X, Wu C, Peng H, et al. Effect of Sb and Al-3P complex modification on solidified microstructure and mechanical property of hypereutectic Al-18Si alloys [J]. Physics of Metals and Metallography, 2024: 1-9.
[14] Shi W X. Effect of P on the as-cast organization and mechanical properties of hypereutectic A390 alloy [J]. Foundry, 022, 71 (03): 331-335.
[15] Zhang R Y, Li J X, Sha J H. Effect of Sr content on microstructure and thermal conductivity of Al-Si alloy [J]. Journal of Heat Treatment of Materials, 2024, 45(1): 53-61.
[16] Li Y X, Li Z L, Wang Q, et al. Study on the mechanism of modification and refinement of Al-25%Si alloy by Al-Si-P Master Alloy[J]. Foundry, 2020, 69(1): 35-39.
[17] Nogita K, McDonald S D, Dahle A K. Eutectic modification of Al-Si alloys with rare earth metals[J]. Materials transactions, 2004, 45(2): 323-326.
[18] Alkahtani S A, Elgallad E M, Tash M M, et al. Effect of rare earth metals on the microstructure of Al-Si based alloys [J]. Materials, 2016, 9(1): 45.
[19] Chang J, Moon I, Choi C. Refinement of cast microstructure of hypereutectic Al-Si alloys through the addition of rare earth metals[J]. Journal of Materials Science, 1998, 33: 5015-5023.
[20] Fang J Q. Study on microstructure and properties of hypereutectic Al-Si alloy by mechanical stirring method and Yb modification [D]. East China University of Technology, 2023.
[21] Liu N C, Li J Q, Liu Z X. Effect of compound modification on structure of hypereutectic Al-Si alloy[J]. Advanced Materials Research, 2011, 160: 189-193.
[22] Liu N C, Kang G S, Liu Z X. Effect of compound modification on microstructure and properties of high silicon aluminum alloy[J]. Advanced Materials Research, 2012, 476: 114-117.
[23] Teng H L, Shi W X, He H Y. Preparation of Al-10%LaCe intermediate alloy and its metamorphism on Hypereutectic Al-Si alloy [J]. Journal of Liaoning University of Science and Technology, 2023, 25(5): 14-17.
[24] He H Y. Effect of P-LaCe composite metamorphism on hypereutectic Al-25%Si alloy [J]. China National Knowledge Net, 2023, 25(06): 1-3.
[25] Li J W, Wang A Q, Xie J P, et al. The microstructure characteristics and wear resistance of rapidly solidified hypereutectic Al-Si alloys[C]. Materials Science Forum, 2010, 654: 986-989.
[26] Cai Z, Wang R, Zhang C, et al. Characterization of rapidly solidified Al-27Si hypereutectic alloy: effect of solidification condition[J]. Journal of Materials Engineering and Performance, 2015, 24: 1226-1236.
[27] Li Y, Jiang T, Wei B, et al. Microcharacterization and mechanical performance of an Al-50Si alloy prepared using the sub-rapid solidification technique[J]. Materials Letters, 2020, 263: 127287.
[28] Xue L Q. Effect of alloying elements and cooling Rate on solidification microstructure of hypereutectic Al-Si alloy [D]. Liaoning University of Technology, 2016.
[29] Li Y F. Microstructure evolution of high-silicon aluminum alloy prepared by continuous extrusion by jet deposition [D]. Kunming University of Science and Technology, 2022.
[30] Yu S R, Feng H K, Li Y L, et al. Study on the properties of Al-23%Si alloy treated by ultrasonic wave[J]. Journal of Alloys and Compounds, 2009, 484(1-2): 360-364.
[31] Ünal N, Çamurlu H E, Koçak S, et al. Effect of external ultrasonic treatment on hypereutectic cast aluminium–silicon alloy [J]. International Journal of Cast Metals Research, 2012, 25(4): 246-250.
[32] He W, Ma H, Wang L M. Effect of high power and longtime ultrasonic melt treatment on microstructure of Al-Si alloy [J]. Hot Working Technology, 2023, 52(19): 53-57.
[33] Chen X. Effect of external field treatment and heat treatment on microstructure and properties of Al-25%Si alloy [D]. Xian Technological University, 2021.
[34] Brabazon D, Browne D J, Carr A J. Mechanical stir casting of aluminium alloys from the mushy state: process, microstructure and mechanical properties[J]. Materials Science and Engineering: A, 2002, 326(2): 370-381.
[35] Zhuang L Z, Xu Y, Yan Y B. Effect of mechanical mixing process on primary Si microstructure of Al-30Si Alloy [J]. Special Casting and Non-Ferrous Alloys, 2016, 36(9): 988-991.
[36] Manani S, Pradhan A K. Effects of melt thermal treatment on cast Al-Si alloys: A review [J]. Materials Today: Proceedings, 2022, 62: 6568-6572.
[37] Zhou Z P, Li R D. Domestic development of superheat treatment of alloy melt [J]. Foundry, 2003, (02):79-83.
[38] Yang K W, Liu S Q, Xu J S. Effect of melt superheating on morphology of primary silicon in Al-18%Si alloy [J]. Aluminum Processing, 2020, (6): 13-15.
[39] Lu N F. Study on the preparation, microstructure and properties of Al-30%Si alloy [D]. Hefei University of Technology, 2022.
[40] Liao X L, Gong Y Y, Li R X, et al. Effect of pulse magnetic field on solidification structure and properties of pure copper[J]. Research & Development, 2007.
[41] Kasprzak W, Chen D L, Shaha S K. Heat treatment development for a rapidly solidified heat resistant cast Al-Si alloy [J]. Journal of Materials Engineering and Performance, 2013, 22: 1839-1847.
[42] Liang B, Zhang Z F, Chen C S, et al. Effect of homogenization annealing on microstructure and properties of hypereutectic Al-17Si Alloy [J]. Heat Treatment of Metals, 2009, 34(12): 18-22.
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