A New Water-Soluble Supramolecular Container for Efficient Separation and Storage of Gasoline Components
DOI: 10.23977/analc.2024.030110 | Downloads: 6 | Views: 398
Author(s)
He Xuxiang 1
Affiliation(s)
1 Xi'an High-Tech No.1 School, Xi'an, China
Corresponding Author
He XuxiangABSTRACT
This study explores the development of a low-energy, low-pollution, and efficient gasoline fraction separation technology using a water-soluble organometallic supramolecular cage. With the growing demand for petroleum and the environmental challenges posed by traditional extraction methods, this research aims to improve the efficiency of gasoline extraction from crude oil. A hybrid metal-organic cage was synthesized using a ligation-driven self-assembly strategy, featuring a specific cavity that selectively screens gasoline fractions based on molecular size and shape. The experimental process involved separating simulated gasoline, commercial gasoline, and crude oil, demonstrating the cage's potential for selective extraction. The findings contribute to advancements in separation technologies for the petrochemical industry and offer a pathway toward more sustainable petroleum refining processes.
KEYWORDS
Petroleum refining, Supramolecular cage, Gasoline fraction fiseparation, Metal-organic cage, Crude oil separationCITE THIS PAPER
He Xuxiang, A New Water-Soluble Supramolecular Container for Efficient Separation and Storage of Gasoline Components. Analytical Chemistry: A Journal (2024) Vol. 3: 54-61. DOI: http://dx.doi.org/10.23977/analc.2024.030110.
REFERENCES
[1] Sholl, D. S.; Lively, R. P. Seven Chemical Separations to Change the World[J].Nature, 2016, 532, 435−437.
[2] Yadav A., Gupta A. K., Steiner A., et al. Mapping the Assembly of Metal–Organic Cages into Complex Coordination Networks[J]. Chem.−Eur. J.,2017, V23(72): 18296-18302.
[3] Sun Y., Yao Y., Wang H., et al. Self-Assembly of Metallacages intoMultidimensional Suprastructures with Tunable Emissions. J. Am. Chem. Soc.,2018, V140(40): 12819-12828.
[4] Fang Y., Lian X. Z., Huang Y. Y., et al. Investigating Subcellular Compartment Targeting Effect of Porous Coordination Cages for Enhancing Cancer Nanotherapy[J]. Small, 2018, V14(47): 1802709.
[5] Fang Y., Xiao Z. F., Li J. L., et al. Formation of a Highly Reactive Cobalt Nanocluster Crystal within a Highly Negatively Charged Porous Coordination Cage[J]. Angew. Chem. Int. Ed., 2018, 57(19): 5283-5287.
[6] Pasquale S., Sattin S., Escudero-Adán E. C., et al. Giant Regular Polyhedra from Calixarene Carboxylates and Uranyl[J]. Nat. Commun., 2012, V(3): 785.
[7] Gropp C., Quigley B. L., Diederich F. Molecular Recognition with Resorcin arene Cavitands: Switching, Halogen-Bonded Capsules, and Enantioselective Complexation[J]. J. Am. Chem. Soc., 2018, V140(8):2705-2717.
[8] Fox O. D., Cookson J., Wilkinson E. J. S., et al. Nanosized Polymetallic Resorcinarene-Based Host Assemblies that Strongly Bind Fullerenes[J]. J. Am. Chem. Soc., 2006, V128(21): 6990-7002.14
[9] Turunen L., Warzok U., Puttreddy R., et al. [N⋅ ⋅ ⋅ I+⋅ ⋅ ⋅ N] Halogen-Bonded Dimeric Capsules from Tetrakis (3-pyridyl) ethylene Cavitands [J]. Angew. Chem. Int. Ed., 2016, V55 (45): 14033-14036.
[10] Stricklen P., Verkade J. Novel Homo and Heterometallic Coordination Macrocycles[J]. J. Am. Chem. Soc., 1983, V105 (8): 2494-2495.
[11] Fujita M. Metal-Directed Self-Assembly of Two- and Three-Dimensional Synthetic Receptors[J]. Chem. Soc. Rev., 1998, V27 (6): 417-425.
[12] Stang P. J., Olenyuk B. Self-Assembly, Symmetry, and Molecular Architecture: Coordination as the Motif in the Rational Design of Supramolecular Metallacyclic Polygons and Polyhedra[J]. Acc. Chem. Res., 1997, V30(12): 502-518.
[13] Caulder D. L., Raymond K. N. Supermolecules by Design[J]. Acc. Chem. Res., 1999, V32(11): 975-982.
[14] Fujita M., Umemoto K., Yoshizawa M., et al. Molecular Paneling via Coordination[J]. Chem. Commun., 2001, V(6): 509-518.
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